Unveil the mechanisms driving correlated alkali ion and proton transport in polymers.
The goal of this Thrust is to understand and realize new mechanisms of superionic conductivity (Li+, Na+, H+) in polymer-based materials (i.e., > 1 mS/cm at room temperature).
Key questions:
- What are the fundamental physics controlling charge transport in polymers and what are the microscopic mechanisms that determine energy barriers for ion hopping?
- Why does correlated ion motion suppress charge transport in polymeric materials, while it enhances charge transport in superionic glasses?
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Theoretically Unveiling the Factors that Control the Activated Ion Mobility in Lithium-Based Polymerized Ionic Liquids and Glasses
ACS Cent. Sci. 2026, 12, 658
Publication Date: 20260504 -

Understanding the Influence of Chain Architecture on the Transport Quantities of Polymer Electrolytes with Covalently Bonded Anions
ACS Appl. Energy Mater. 2026, 9, 1045
Publication Date: 20260108 -

Real-space local dynamics in 1,2,3-triazole using inelastic neutron scattering
J. Phys. Chem. B 2025, 129, 12330
Publication Date: 20251101 -

A Solid State Zwitterionic Plastic Crystal with High Static Dielectric Constant
Adv. Mat. 2026, 38, e17774
Publication Date: 20260116 -

Temperature Evolution of the Activation Barriers Leads to Meyer−Neldel Rules for Structural Relaxation and Transport in Polymers
Macromolecules 2025 58, 13504
Publication Date: 20251211 -

Structural Correlations Control Collective Contributions to the Conductivity of Polymerized Ionic Liquids
Macromolecules 2025, 58, 11476
Publication Date: 20250910